Synthesis and characterization of new SILVER(I) coordination polymers incorporating a BIS(TRIAZOLYL)-type ligand

Authors

  • Nertil Xhaferaj University of Tirana image/svg+xml
  • Aurel Tăbăcaru “Dunarea de Jos“ University of Galati
  • Claudio Pettinari University of Camerino

DOI:

https://doi.org/10.35219/ann-ugal-math-phys-mec.2018.2.02

Keywords:

coordination polymers, bis(triazolyl) ligand, silver, counteranions, infrared spectra

Abstract

This paper reports the synthesis and characterization of six new coordination polymers having the following stoechiometric formulations: Ag2(tr2ad)(NO 3)2·H2O (1), Ag3(tr2ad)2(ClO4)3·EtOH (2), Ag(tr2ad)(PF6)·H2O (3), Ag3(tr2ad)2(BF4)3·H2O (4), Ag2(tr2ad)(CH3SO3)2·3H2O (5) and Ag3(tr2ad)2(CF3SO3)3·EtOH (6) (EtOH = ethanol). The compounds were obtained from the interaction between the 1,3-bis(1,2,4-triazol-4-yl) adamantane ligand (tr2ad) and silver(I) salts with different counteranions, in alcoholic ambient at room temperature. All the compounds are air- and moisture-stable, insoluble in most common solvents and do not melt, but only decompose upon heating to high temperatures, thus suggesting their polymeric nature. Fourier transform infrared spectroscopy (FTIR) was employed in order to reveal both the changes in the absorbtion bands of the ligand upon coordination to silver(I) ions and the binding modes of the counteranions.

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Author Biographies

  • Nertil Xhaferaj, University of Tirana

    Agriculture University of Tirana, Kodër Kamëz, SH1, Tirana 1000, Albania

    School of Pharmacy, University of Camerino, Via S. Agostino 1, 62032 Camerino (MC), Italy

  • Aurel Tăbăcaru, “Dunarea de Jos“ University of Galati

    Department of Chemistry, Physics and Environment, Faculty of Sciences and Environment, “Dunarea de Jos” University of Galati, Romania

  • Claudio Pettinari, University of Camerino

    School of Pharmacy, University of Camerino, Via S. Agostino 1, 62032 Camerino (MC), Italy

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Published

2018-11-21

Issue

Vol. 41 No. 2 (2018)

Section

Articles

How to Cite

“Synthesis and characterization of new SILVER(I) coordination polymers incorporating a BIS(TRIAZOLYL)-type ligand” (2018) Analele Universității ”Dunărea de Jos” din Galați. Fascicula II, Matematică, fizică, mecanică teoretică / Annals of the ”Dunarea de Jos” University of Galati. Fascicle II, Mathematics, Physics, Theoretical Mechanics, 41(2), pp. 128–134. doi:10.35219/ann-ugal-math-phys-mec.2018.2.02.